کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5222432 1383454 2009 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
1,2-Cyclic sulfite and sulfate furanoside diesters: improved syntheses and stability
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
1,2-Cyclic sulfite and sulfate furanoside diesters: improved syntheses and stability
چکیده انگلیسی

The facile syntheses of 1,2- and 3,5-cyclic sulfite and sulfate furanoside diesters were conducted in molecular solvents and ionic liquids in the presence of immobilised morpholine. Molecular solvents and ionic liquids performed similarly with regards to overall yields. However, the use of ILs allowed for the reactions to be carried out under atmospheric conditions and showed good recyclability. Additionally, increases in product stability was achieved in ILs over organic solvents, in particular, in bis{(trifluoromethanesulfonyl)imide} and trispentafluoro-ethyltrifluorophosphate-based ionic liquids, which were also excellent media to control the hydrolysis of thionyl chloride and sulfuryl chloride.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 65, Issue 32, 8 August 2009, Pages 6341-6347
نویسندگان
, , , , ,