کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5222977 1383473 2009 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Convenient and efficient Suzuki-Miyaura cross-coupling reactions catalyzed by palladium complexes containing N,N,O-tridentate ligands
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Convenient and efficient Suzuki-Miyaura cross-coupling reactions catalyzed by palladium complexes containing N,N,O-tridentate ligands
چکیده انگلیسی
The experimental and DFT studies on the Suzuki reaction catalyzed by palladium complexes with N,N,O-tridentate ligands revealed that the catalytic performance may differ greatly upon a small variation in the structure of the ligand. Comparison of the optimized geometries of the presumed reaction intermediates, TS4a and TS4b, showed that a bulkier group, tBu, in TS4b exerts a greater steric effect on the nearby phenoxide moiety than a smaller -OMe group does in TS4a.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 65, Issue 15, 11 April 2009, Pages 2889-2897
نویسندگان
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