کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5223786 | 1383498 | 2010 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Chiral eighteen-component three-dimensional supramolecular entities stabilized by the hydrogen bonding and coordination interactions Chiral eighteen-component three-dimensional supramolecular entities stabilized by the hydrogen bonding and coordination interactions](/preview/png/5223786.png)
A new class of chiral eighteen-component three-dimensional supramolecular entities has been assembled in toluene and chloroform from twelve zinc porphyrin-appended 2-(ethylamino)- pyrimido[4,5-b][1,8]naphthyridin-4(3H)-one monomers and six chiral bipyridyl compounds. The heterocyclic segments form two C6-symmetric cyclic hexamers, which are stabilized by a well-established DDA-AAD hydrogen bonding motif, while the six chiral bispyridine ligands are coordinated to the corresponding zinc porphyrin units to give the two-layered architectures. The structures have been characterized by the 1H NMR, UV-vis and circular dichroism experiments, which also reveals that, when the concentration of the monomers is high enough, the chiral supramolecular entity can be formed exclusively.
Journal: Tetrahedron - Volume 66, Issue 23, 5 June 2010, Pages 4057-4062