کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5224551 1383521 2009 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A DMAP-functionalized oligocholate foldamer for solvent-responsive catalysis
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
A DMAP-functionalized oligocholate foldamer for solvent-responsive catalysis
چکیده انگلیسی

A hexameric cholate foldamer functionalized with a 4-dialkylaminopyridyl group displayed solvent-sensitive catalysis for the acetylation of alcohols. The catalyst folded in carbon tetrachloride containing a low percentage (<4%) of DMSO and unfolded as more DMSO was added. By increasing the effective concentration of the substrate near the catalytic group, the folded catalyst was more active than the unfolded catalyst toward small, hydrophilic alcohols. The longer and hydrophobic n-octanol, however, was more reactive in the presence of the unfolded catalyst. The highest selectivity (21:1) was observed for methanol/n-octanol with the folded oligocholate catalyst.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 65, Issue 35, 29 August 2009, Pages 7311-7316
نویسندگان
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