کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5225038 | 1383536 | 2007 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Palladium(II) mediated aziridination of olefins with bromamine-T as the nitrogen source: scope and mechanism
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Palladium(II) mediated aziridination of olefins with bromamine-T as the nitrogen source: scope and mechanism Palladium(II) mediated aziridination of olefins with bromamine-T as the nitrogen source: scope and mechanism](/preview/png/5225038.png)
چکیده انگلیسی
The palladium(II)-promoted reaction of a variety of olefins and bromamine-T provided N-tosyl-2-substituted aziridines under mild conditions. Olefins bearing chiral appendages gave only a poor to modest diastereoselectivity. Appropriate deuterated olefins were selected to study the stereochemistry of the reaction. A Pd(IV) intermediate is proposed as the aziridinating species.
A simple method is described for the palladium(II) mediated aziridination of a broad range of olefins using bromamine-T as the nitrogen source.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 63, Issue 30, 23 July 2007, Pages 7009-7017
Journal: Tetrahedron - Volume 63, Issue 30, 23 July 2007, Pages 7009-7017
نویسندگان
Alexandra M.M. Antunes, Vasco D.B. Bonifácio, Susana C.C. Nascimento, Ana M. Lobo, Paula S. Branco, Sundaresan Prabhakar,