کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5225039 1383536 2007 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Molecular machines: synthesis and characterization of two prototypes of molecular wheelbarrows
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Molecular machines: synthesis and characterization of two prototypes of molecular wheelbarrows
چکیده انگلیسی

Technomimetic molecules are molecules designed to imitate macroscopic objects at the molecular level, also transposing the motions that these objects are able to undergo. This article focuses on the synthesis of two polyaromatic hydrocarbons designed by analogy with macroscopic wheelbarrows. The molecular wheelbarrows are synthesized following a modular strategy based on sequential double Knoevenagel and Diels-Alder reactions. Our strategy allowed to easily vary the chemical nature of the handles, which is crucial for subsequent manipulation with an STM tip.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 63, Issue 30, 23 July 2007, Pages 7018-7026
نویسندگان
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