کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5225045 | 1383536 | 2007 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Sulfur-containing dihydro-pyrrolo [60]fullerene derivatives via 1,3-dipolar cycloadditions of glycine imine esters to C60
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Sulfur-containing dihydro-pyrrolo [60]fullerene derivatives via 1,3-dipolar cycloadditions of glycine imine esters to C60 Sulfur-containing dihydro-pyrrolo [60]fullerene derivatives via 1,3-dipolar cycloadditions of glycine imine esters to C60](/preview/png/5225045.png)
چکیده انگلیسی
C60 reacts thermally with 1,3-dipoles, formed in situ, from sulfide-bearing imines of glycine esters, and affords dihydro-pyrrolo [60]fullerene derivatives containing a vinylic sulfide group, which were isolated in good yields, and characterized with 1H and 13C NMR, FTIR, UV-vis spectroscopies, and with FAB, ESI mass spectrometries. The new derivatives contain a sulfide, an imine, and an ester functionality for further chemical transformations. Mechanistic considerations with regard to the loss of a mercaptan molecule in the course of the cycloaddition are deployed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 63, Issue 30, 23 July 2007, Pages 7070-7076
Journal: Tetrahedron - Volume 63, Issue 30, 23 July 2007, Pages 7070-7076
نویسندگان
Evaggelia Ioannou, Andreas Hirsch, Yiannis Elemes,