کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5225045 1383536 2007 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Sulfur-containing dihydro-pyrrolo [60]fullerene derivatives via 1,3-dipolar cycloadditions of glycine imine esters to C60
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Sulfur-containing dihydro-pyrrolo [60]fullerene derivatives via 1,3-dipolar cycloadditions of glycine imine esters to C60
چکیده انگلیسی

C60 reacts thermally with 1,3-dipoles, formed in situ, from sulfide-bearing imines of glycine esters, and affords dihydro-pyrrolo [60]fullerene derivatives containing a vinylic sulfide group, which were isolated in good yields, and characterized with 1H and 13C NMR, FTIR, UV-vis spectroscopies, and with FAB, ESI mass spectrometries. The new derivatives contain a sulfide, an imine, and an ester functionality for further chemical transformations. Mechanistic considerations with regard to the loss of a mercaptan molecule in the course of the cycloaddition are deployed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 63, Issue 30, 23 July 2007, Pages 7070-7076
نویسندگان
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