کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5225384 | 1383546 | 2007 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Parvistemins A-D, a new type of dimeric phenylethyl benzoquinones from Stemona parviflora Wright
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Parvistemins A-D, a new type of dimeric phenylethyl benzoquinones from Stemona parviflora Wright Parvistemins A-D, a new type of dimeric phenylethyl benzoquinones from Stemona parviflora Wright](/preview/png/5225384.png)
چکیده انگلیسی
Four naturally occurring dimeric phenylethyl benzoquinones, parvistemins A-D, were isolated from the aerial parts of Stemona parviflora Wright. Their constitutions were established by spectroscopic methods. Due to restricted rotation about the central biaryl axis, the compounds are chiral, although racemic. Their two respective atropo-enantiomers were resolved by HPLC on a chiral phase and were stereochemically characterized online, in hyphenation with circular dichroism (CD) spectroscopy (LC-CD coupling), combined with quantum chemical CD calculations.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 63, Issue 22, 28 May 2007, Pages 4688-4694
Journal: Tetrahedron - Volume 63, Issue 22, 28 May 2007, Pages 4688-4694
نویسندگان
Xinzhou Yang, Tobias A.M. Gulder, Matthias Reichert, Chunping Tang, Changqiang Ke, Yang Ye, Gerhard Bringmann,