کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5226312 1383572 2006 14 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The allenic Alder-ene reaction: constitutional group selectivity and its application to the synthesis of ovalicin
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
The allenic Alder-ene reaction: constitutional group selectivity and its application to the synthesis of ovalicin
چکیده انگلیسی

The scope of the novel allenic Alder-ene reaction using Rh(I) and Ir(I) catalysts has been extended to differentially substituted 1,1,3-trisubstituted allenes. This allenyl substitution pattern can give three possible cross-conjugated triene products. The selectivity of this transformation can be controlled by varying reaction temperature, solvent, and catalyst. Progress toward the synthesis of ovalicin using this triene forming protocol is described.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 62, Issue 45, 6 November 2006, Pages 10541-10554
نویسندگان
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