کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5227490 | 1383607 | 2006 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
First stereoselective synthesis of potassium aeschynomate and its no-natural stereomers
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
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![عکس صفحه اول مقاله: First stereoselective synthesis of potassium aeschynomate and its no-natural stereomers First stereoselective synthesis of potassium aeschynomate and its no-natural stereomers](/preview/png/5227490.png)
چکیده انگلیسی
The synthesis of potassium aeshynomate and its non-natural stereomers was achieved using the Sharpless catalytic asymmetric dihydroxylation of (Z) or (E) vinylogous glycine as the key step. The resulting γ-amino α,β-dihydroxyester stereomer was deprotected and coupled with the caffeic acid to afford stereoselectively potassium aeshynomate or its stereomers. A detailed study of the NMR data of the different stereomers is reported that corrects the literature data.
Graphical Abstract
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 62, Issue 8, 20 February 2006, Pages 1787-1798
Journal: Tetrahedron - Volume 62, Issue 8, 20 February 2006, Pages 1787-1798
نویسندگان
Stéphanie Claudel, Tomasz Krzysztof Olszewski, Pierre Mutzenardt, Christie Aroulanda, Philippe Coutrot, Claude Grison,