کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5227716 1383614 2009 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis, binding properties and theoretical studies of p-tert-butylhexahomotrioxacalix[3]arene tri(adamantyl)ketone with alkali, alkaline earth, transition, heavy metal and lanthanide cations
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Synthesis, binding properties and theoretical studies of p-tert-butylhexahomotrioxacalix[3]arene tri(adamantyl)ketone with alkali, alkaline earth, transition, heavy metal and lanthanide cations
چکیده انگلیسی
A new hexahomotrioxacalix[3]arene triketone (1b) was synthesized and isolated in a cone conformation in solution at room temperature, as established by NMR (1H and 13C). The binding properties of 1b towards alkali, alkaline earth, transition, heavy metal and lanthanide cations have been assessed by phase transfer and proton NMR titrations. Molecular mechanics and ab initio techniques were also performed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 65, Issue 2, 10 January 2009, Pages 496-503
نویسندگان
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