کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5228040 1383622 2007 14 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Sparsely substituted chlorins as core constructs in chlorophyll analogue chemistry. Part 1: Synthesis
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Sparsely substituted chlorins as core constructs in chlorophyll analogue chemistry. Part 1: Synthesis
چکیده انگلیسی

Five routes to stable chlorins bearing 0 or 1 meso substituents have been investigated, among which reaction of a 9-bromo-1-formyldipyrromethane and 2,3,4,5-tetrahydro-1,3,3-trimethyldipyrrin proved most effective. Application of this route afforded metallochlorins [Cu(II), Zn(II), and Pd(II)] including the chlorin lacking any β-pyrrole and meso substituents.

New synthetic routes provide access to metallochlorins bearing 0 or 1 meso-aryl substituents.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 63, Issue 18, 30 April 2007, Pages 3826-3839
نویسندگان
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