|کد مقاله||کد نشریه||سال انتشار||مقاله انگلیسی||ترجمه فارسی||نسخه تمام متن|
|5228790||1383643||2018||10 صفحه PDF||سفارش دهید||دانلود کنید|
An improved zirconium-mediated alkyne-aldehyde cross-coupling reaction has been achieved to afford the stereodefined (Z)-allylic alcohols or 3-iodinated allylic alcohols selectively via protonolysis or iodinolysis of the corresponding five-membered oxazirconacycles. This method has also been successfully applied to the synthesis of (Z)-enynols through cross-coupling reactions of three different components involving alkyne, aldehyde, and alkynyl bromide in a one-pot procedure.
Journal: Tetrahedron - Volume 63, Issue 9, 26 February 2007, Pages 2009-2018