کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5228909 1383646 2008 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electron transfer in the cathodic reduction of α-dicarbonyl compounds
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Electron transfer in the cathodic reduction of α-dicarbonyl compounds
چکیده انگلیسی

Electron transfer processes take place during the cathodic reduction, under an argon atmosphere, of different α-dicarbonyl substrates. Carboxylic acids or methylene diesters are obtained from benzil or furil after electron transfer to the oxygen in the air, during the workup, or after electron transfer to the solvent. Involving an electron transfer to dichloromethane, 2-hydroxy-2-hydroxymethyl-2H-acenaphtylen-1-one or benzo[1,3]dioxin-8-one are formed when acenaphthenequinone or 1,2-cyclohexanedione are, respectively, reduced.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 64, Issue 8, 18 February 2008, Pages 1834-1838
نویسندگان
, ,