کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5229817 1383673 2007 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Aerobic oxidation of alcohol in aqueous solution catalyzed by gold
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Aerobic oxidation of alcohol in aqueous solution catalyzed by gold
چکیده انگلیسی

The heterogeneous oxidation catalyzed by supported gold nanoparticles has been relatively well studied. In comparison, the oxidation of alcohols catalyzed by ligand-supported gold complexes was rarely reported. Herein a general method is demonstrated to oxidize secondary and primary benzyl and allylic alcohols to carbonyl compounds via Au(I) catalyzed reaction in air and water. Primary mechanistic studies indicated that the catalytic pathway is different from those catalyzed by solid-supported gold nanoparticles.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 63, Issue 35, 27 August 2007, Pages 8430-8434
نویسندگان
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