کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
52574 | 46877 | 2007 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
High performance of Ni-substituted calcium aluminosilicate for partial oxidation of methane into syngas
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
Newly synthesized calcium aluminosilicate, in which oxide anions were occluded, was tested as a catalyst for partial oxidation of CH4 into CO and H2. Substitution of a part of Ca2+ with Ni2+ resulted in a marked increase in CH4 conversion (93% at 800 °C) and in CO and H2 selectivities (94% and 95%, respectively), while Cr3+, Co3+, Fe3+ and Cu2+ slightly increased CH4 conversion with a considerable decrease in CO and H2 selectivities. Such a high performance may be attributed to the ability of Ni-substituted sample for CH4 steam reforming appearing during CH4 partial oxidation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 8, Issue 11, November 2007, Pages 1735–1738
Journal: Catalysis Communications - Volume 8, Issue 11, November 2007, Pages 1735–1738
نویسندگان
Katsuya Sato, Satoru Fujita, Kenzi Suzuki, Toshiaki Mori,