کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5262481 1385183 2014 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Stereoselective total synthesis of (+)-boronolide, (+)-anamarine, 8-epi-spicegerolide
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Stereoselective total synthesis of (+)-boronolide, (+)-anamarine, 8-epi-spicegerolide
چکیده انگلیسی
A stereoselective total synthesis of the naturally occurring cytotoxic lactones (+)-boronolide, (+)-anamarine, and 8-epi-spicigerolide is described. d-Xylose has been used as a chiral source to construct the four contiguous oxygenated stereogenic centers of target molecules. The diastereoselective allylation was performed using Brown's protocol and the lactone moiety was prepared by ring closing metathesis.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 55, Issue 8, 19 February 2014, Pages 1398-1401
نویسندگان
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