کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
52626 | 46879 | 2006 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Oxidative dehydrogenation of ethane to ethylene by carbon dioxide over Cr/TS-1 catalysts
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A series of chromium catalysts supported on titanosilicate-1 (TS-1) molecular sieves with different nSi/nTi ratios prepared by impregnation method have been tested for the dehydrogenation of ethane with carbon dioxide between 450 and 650 °C. The results showed that Cr/TS-1 (nSi/nTi = 30) catalyst effectively dehydrogenated ethane to ethylene in the presence of carbon dioxide at 650 °C, giving 47.4% ethylene yield with a selectivity of 90.0%. The catalytic activity, observed at temperatures as low as 450 °C can be well explained on the basis of the existence of reducible chromium species. Moreover, the catalytic stability and regeneration performance of the Cr/TS-1 (nSi/nTi = 30) catalyst were also investigated.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 7, Issue 9, September 2006, Pages 633–638
Journal: Catalysis Communications - Volume 7, Issue 9, September 2006, Pages 633–638
نویسندگان
Xinhong Zhao, Xiaolai Wang,