کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5264251 1385247 2014 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Enormously extended π-electronic conjugation system of dimeric octaethylporphyrin transmitted with anthracene
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Enormously extended π-electronic conjugation system of dimeric octaethylporphyrin transmitted with anthracene
چکیده انگلیسی
Based on the fact that anthracene (Anth) possesses much higher similarity in electron-releasing ability to porphyrin nucleus than the other polyacenes, the dimeric octaethylporphyrin (OEP) derivatives 4 and 5 (OEP-Anth-OEP) were synthesized and their structure-property relationships were examined, as compared with related OEP dimers 1-3. Among them, the derivative 4 showed enormously high electronic communication between two terminal OEP rings, potentially providing a suitable unit of the electronic structure for molecular design of the OEP devices operating with less energy and with higher sensitivity to outside stimuli.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 55, Issue 37, 10 September 2014, Pages 5164-5169
نویسندگان
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