کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5264251 | 1385247 | 2014 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Enormously extended Ï-electronic conjugation system of dimeric octaethylporphyrin transmitted with anthracene
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
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چکیده انگلیسی
Based on the fact that anthracene (Anth) possesses much higher similarity in electron-releasing ability to porphyrin nucleus than the other polyacenes, the dimeric octaethylporphyrin (OEP) derivatives 4 and 5 (OEP-Anth-OEP) were synthesized and their structure-property relationships were examined, as compared with related OEP dimers 1-3. Among them, the derivative 4 showed enormously high electronic communication between two terminal OEP rings, potentially providing a suitable unit of the electronic structure for molecular design of the OEP devices operating with less energy and with higher sensitivity to outside stimuli.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 55, Issue 37, 10 September 2014, Pages 5164-5169
Journal: Tetrahedron Letters - Volume 55, Issue 37, 10 September 2014, Pages 5164-5169
نویسندگان
Hideto Kempe, Natsuki Kuroda, Junro Yoshino, Naoto Hayashi, Hiroyuki Higuchi,