کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
52672 | 46880 | 2007 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Amination of ethanolamine over cobalt modified H-ZSM-5 catalysts
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
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چکیده انگلیسی
The amination of ethanolamine (EA) with ammonia proceeded over a cobalt modified H-ZSM-5 under rather moderate conditions in a fixed-bed reactor. These catalysts were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, temperature-programmed reduction, and infra-red spectroscopy. The reaction mechanism was also discussed, and Co0 is believed to be the active site of the hydrogenation/dehydrogenation process and the acid sites of H-ZSM-5 is thought to be the active site of the amination process. Thus, the synergetic effect of the cobalt and the acidic sites of H-ZSM-5 is necessary for the amination of ethanolamine.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 8, Issue 7, July 2007, Pages 1102–1106
Journal: Catalysis Communications - Volume 8, Issue 7, July 2007, Pages 1102–1106
نویسندگان
Yuecheng Zhang, Guoyi Bai, Xilong Yan, Yang Li, Tao Zeng, Juan Wang, Hefang Wang, Junde Xing, Dezhi Luan, Xinyu Tang, Ligong Chen,