کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5267322 1385335 2015 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Iridium and phosphine promoted C-F bond activation: the C-S cross-coupling of aryl fluorides with diaryl disulfides to synthesize thioethers
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Iridium and phosphine promoted C-F bond activation: the C-S cross-coupling of aryl fluorides with diaryl disulfides to synthesize thioethers
چکیده انگلیسی
Carbon-fluorine bond is the strongest known single bond to carbon and proved very difficult to cleave. An iridium and phosphine promoted C-F bond activation was developed, for the first time achieving the C-S cross-coupling reaction of disulfides with aryl fluorides using iridium complex. The corresponding monoarylthiolation products were obtained at moderate to good yields. Thus, it represents a new method for the synthesis of aryl sulfides through C-F bond activation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 56, Issue 46, 18 November 2015, Pages 6405-6408
نویسندگان
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