کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5267892 1385349 2012 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A tandem olefin migration and Prins cyclization using Cu(OTf)2-bisphosphine complexes: an improved synthesis of functionalized tetrahydropyrans
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
A tandem olefin migration and Prins cyclization using Cu(OTf)2-bisphosphine complexes: an improved synthesis of functionalized tetrahydropyrans
چکیده انگلیسی
In situ-generated (bis-DPPMB)-Cu(OTf)2 complex has been examined to catalyze a tandem olefin migration and Prins cyclization of an alkenol with various aldehydes. The reaction proceeded with electron-rich aromatic aldehydes at room temperature and provided functionalized tetrahydropyrans in good yields. An efficient synthesis of the bis-DPPMB ligand has also been described.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 53, Issue 29, 18 July 2012, Pages 3699-3702
نویسندگان
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