A simple synthesis of 4-substituted 2,3-benzoxazinones from C-2 arylated 1,3-indanediones

A simple one-pot procedure for the conversion of 2-hydroxy-2-(2′-hydroxy-aryl)-1,3-indanediones to 4-substituted benzoxazinones has been developed. The process constitutes an interesting acid-catalyzed rearrangement followed by condensation with hydroxylamine.

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