کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5269052 | 1385380 | 2014 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Metal-free regioselective hydrobromination of alkynes through CH/CBr activation
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Metal-free regioselective hydrobromination of alkynes through CH/CBr activation Metal-free regioselective hydrobromination of alkynes through CH/CBr activation](/preview/png/5269052.png)
چکیده انگلیسی
A metal-free regioselective hydrobromination of alkynes has been developed to provide the Markovnikov-type vinyl bromides in good yields using dibromomethane/N,N-dimethylaniline as in-situ 'HBr' source. This protocol also represents an elegant example of the activation of sp2 CH and CBr bonds in one pot, in which 'HBr' is generated and transferred under mild metal-free conditions. D-incorporated experiments were employed to investigate the reaction mechanism and a plausible reaction path was proposed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 55, Issue 33, 13 August 2014, Pages 4572-4575
Journal: Tetrahedron Letters - Volume 55, Issue 33, 13 August 2014, Pages 4572-4575
نویسندگان
Xiuling Chen, Tieqiao Chen, Yuqiang Xiang, Yongbo Zhou, Daoqing Han, Li-Biao Han, Shuang-Feng Yin,