کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5271078 1385432 2014 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Recent advance in transition-metal-mediated trifluoromethylation for the construction of C(sp3)-CF3 bonds
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Recent advance in transition-metal-mediated trifluoromethylation for the construction of C(sp3)-CF3 bonds
چکیده انگلیسی


- We focus on the cases of transition-metal-mediated C(sp3)-CF3 bond formation.
- Trifluoromethylation of sp3-hybridized C-X bonds.
- Trifluoromethylation of alkyl organometallic reagents.
- Trifluoromethylation of sp3-hybridized C-H Bonds.
- Trifluoromethylation of alkene to form C(sp3)-CF3 bonds.

In the past 5 years, transition-metal-mediated trifluoromethylation for the construction of various CF3-containing building blocks has been the focus of recent research in both industrial and academic communities. Progresses in the construction of C(sp2)-CF3 bonds and C(sp)-CF3 have been well reviewed. This Letter will focus on the cases of transition-metal-mediated C(sp3)-CF3 bond formation, which involves the trifluoromethylation of sp3-hybridized C-X bonds, alkyl organometallic reagents, sp3-hybridized C-H bonds, and alkene derivatives.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 55, Issue 3, 15 January 2014, Pages 585-594
نویسندگان
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