کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5271837 | 1385449 | 2010 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Strain in [n]triangulanes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Strain in [n]triangulanes Strain in [n]triangulanes](/preview/png/5271837.png)
چکیده انگلیسی
The molecular structures and strain energies of some [n]triangulanes have been studied by high-level ab initio calculations and compared with results for [n]ladderanes. The calculations provided several unexpected results. We show that the strain energies in triangulanes are smaller than previously suggested. The estimated strain energies in individual rings reveal that those with a larger number of proximal C-C bonds (inner rings) are more strained than peripheral rings with distal bonds. The total electron energies of branched and isomeric unbranched triangulanes are virtually identical. The strain energies of cyclotriangulanes are much smaller than previously estimated which makes them more easily achievable synthetic targets than earlier thought.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 51, Issue 21, 26 May 2010, Pages 2920-2923
Journal: Tetrahedron Letters - Volume 51, Issue 21, 26 May 2010, Pages 2920-2923
نویسندگان
Igor Novak,