کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5273280 | 1385486 | 2008 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Selective fluorescence sensing of cyanide with an o-(carboxamido)trifluoroacetophenone fused with a cyano-1,2-diphenylethylene fluorophore Selective fluorescence sensing of cyanide with an o-(carboxamido)trifluoroacetophenone fused with a cyano-1,2-diphenylethylene fluorophore](/preview/png/5273280.png)
A novel fluorescence probe has been synthesized, which consists of o-(carboxamido)trifluoroacetophenone moiety as the recognition element and cyano-1,2-diphenylethylene moiety as the signaling unit. Fluorescence titrations of the probe with anions such as Fâ, Clâ, Iâ, CNâ, SCNâ, AcOâ, H2PO4-, HSO4-, and ClO4- as their Bu4N+ salts in acetonitrile show that CNâ is the most efficient quencher, AcOâ and Fâ follow it, and other anions show little changes. In an aqueous medium, MeOH-water (9:1), the probe shows fluorescence quenching only toward cyanide and no changes toward the other anions.
A fluorescence probe based on an o-(carboxamido)trifluoroacetophenone binding motif shows selective fluorescence quenching toward cyanide among various anions examined. In particular, the probe responds only to cyanide in aqueous media.
Journal: Tetrahedron Letters - Volume 49, Issue 38, 15 September 2008, Pages 5544-5547