کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5273382 | 1385488 | 2010 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrosynthesis of cholesta-4,6-dien-3-one from cholesterol on a laboratory synthetic scale
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Electrosynthesis of cholesta-4,6-dien-3-one from cholesterol on a laboratory synthetic scale Electrosynthesis of cholesta-4,6-dien-3-one from cholesterol on a laboratory synthetic scale](/preview/png/5273382.png)
چکیده انگلیسی
Cholesterol has been shown to be electrochemically oxidized at a carbon electrode to form cholesta-4,6-dien-3-one in acetonitrile [Hosokawa, Y. Y.; Hakamata, H.; Murakami, T.; Aoyagi, S.; Kuroda, M.; Mimaki, Y.; Itoh, A.; Morosawa, S.; Kusu, F. Electrochim. Acta, 2009, 54, 6412-6416]. To further expand on this reaction in the field of organic synthesis, the electrolysis conditions of cholesterol were optimized on a laboratory synthetic scale. Using a flow-through column electrolysis system, cholesta-4,6-dien-3-one was efficiently produced at the applied potential of 1.9Â V versus Ag/AgCl with a flow rate of 2.5Â mL/min, providing a green tool for the synthesis of cholesta-4,6-dien-3-one.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 51, Issue 1, 6 January 2010, Pages 129-132
Journal: Tetrahedron Letters - Volume 51, Issue 1, 6 January 2010, Pages 129-132
نویسندگان
Yu-Ya Hosokawa, Hideki Hakamata, Tomonori Murakami, Fumiyo Kusu,