Effect of peripheral substitution on the electronic absorption and magnetic circular dichroism (MCD) spectra of metal-free azo-coupled bisphthalocyanine

A new azo-coupled bisphthalocyanine is synthesized from the corresponding quinoxaline oxime which can be obtained by the reaction of s-trans-chloroethanedial with NN conjugated metal-free phthalocyanine. The phthalocyanine is synthesized by the reaction of 4-nitro-o-phenylenediamine with 2-nitro-9,10,16,17,23,24-hexa(hexylthio)phthalocyanine. Novel compounds are characterized by elemental analysis, UV/vis, IR and 1H NMR, and MALDI-TOF spectroscopy. The effect of the azo units on the position and intensity of the electronic absorption and magnetic circular dichroism (MCD) spectra of the bisphthalocyanine are examined for the NN conjugated metal-free phthalocyanine.

A new azo-coupled metal-free bisphthalocyanine is synthesized. The effect of the azo units on the position and intensity of the electronic absorption and magnetic circular dichroism (MCD) spectra of the bisphthalocyanine is described.