کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5275508 | 1385535 | 2008 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
CuCl catalyzed oxidation of aldehydes to carboxylic acids with aqueous tert-butyl hydroperoxide under mild conditions
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Oxidation of aldehydes to the corresponding carboxylic acids can be performed highly efficiently at room temperature with 70% tert-butyl hydroperoxide (in water) in the presence of a catalytic amount of easily available ligand free CuCl in acetonitrile as solvent under very mild conditions. This oxidation protocol works well for various aldehydes including aliphatic aldehydes and aliphatic dialdehydes.
Oxidation of aldehydes to the corresponding carboxylic acids can be performed highly efficiently at room temperature with 70% tert-butyl hydroperoxide (in water) in the presence of a catalytic amount of ligand free CuCl in acetonitrile under very mild conditions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 49, Issue 6, 4 February 2008, Pages 1083-1086
Journal: Tetrahedron Letters - Volume 49, Issue 6, 4 February 2008, Pages 1083-1086
نویسندگان
Sreedevi Mannam, G. Sekar,