کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5275658 1385539 2009 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of a simple chiral auxiliary derived from levoglucosenone and its application in a Diels-Alder reaction
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Synthesis of a simple chiral auxiliary derived from levoglucosenone and its application in a Diels-Alder reaction
چکیده انگلیسی

The synthesis of a chiral alcohol derived from levoglucosenone has been studied. The alcohol was employed as chiral template in an asymmetric Diels-Alder reaction of the corresponding acrylic ester derivative with cyclopentadiene, and was shown to be an efficient asymmetric inductor. The oxidation reaction detected during the hydrogenation of a secondary allylic alcohol intermediate with Pd/C was also investigated.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 50, Issue 9, 4 March 2009, Pages 999-1002
نویسندگان
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