کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5277701 1385586 2007 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Hydrosilylation and double silylation of carbonyl compounds with 1,1′-bis(dimethylsilyl)ferrocene using nickel- and platinum-catalysts
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Hydrosilylation and double silylation of carbonyl compounds with 1,1′-bis(dimethylsilyl)ferrocene using nickel- and platinum-catalysts
چکیده انگلیسی
A series of ferrocene-based organosilicon compounds have been prepared via hydrosilylation or double silylation of carbonyl compounds with 1,1′-bis(dimethylsilyl)ferrocene using (C2H4)Pt(PPh3)2 or Ni(PEt3)4 catalysts. In general, while the platinum catalyst (C2H4)Pt(PPh3)2 preferentially produced cyclic double-silylated products, the Ni(PEt3)4 catalyst led to the hydrosilylated ferrocene products from aldehydes or ketones.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 48, Issue 11, 12 March 2007, Pages 2033-2036
نویسندگان
, , , ,