کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5278752 | 1385611 | 2008 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Four-way-output molecular response system based on the dihydrodibenzo[c,g]phenanthrene skeleton: modulation of CD and FDCD activity by acid and electron-transfer
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Four-way-output molecular response system based on the dihydrodibenzo[c,g]phenanthrene skeleton: modulation of CD and FDCD activity by acid and electron-transfer Four-way-output molecular response system based on the dihydrodibenzo[c,g]phenanthrene skeleton: modulation of CD and FDCD activity by acid and electron-transfer](/preview/png/5278752.png)
چکیده انگلیسی
Presence or absence of electron-accepting dye chromophores is the key function for ON/OFF switching of fluorescence from the dihydrodibenzo[c,g]phenanthrene skeleton in 22+/3. The helical fluorophore in 22+ could be generated stereoselectively upon electrolysis of binaphthylic donor 1 through intramolecular chirality transmission. Huge chiroptical signals are easily detected by circular dichroism (CD) and fluorescence-detected CD (FDCD) techniques to realize novel four-way-output response.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 49, Issue 5, 28 January 2008, Pages 777-781
Journal: Tetrahedron Letters - Volume 49, Issue 5, 28 January 2008, Pages 777-781
نویسندگان
Eisuke Ohta, Tatsuo Nehira, Hidetoshi Kawai, Kenshu Fujiwara, Takanori Suzuki,