کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5279726 | 1385632 | 2007 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Flexible synthesis of vulpinic acids from tetronic acid
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Flexible synthesis of vulpinic acids from tetronic acid Flexible synthesis of vulpinic acids from tetronic acid](/preview/png/5279726.png)
چکیده انگلیسی
Several vulpinic acids were synthesized in a few steps from a single precursor, the tetronic acid. This commercial compound was converted in a few steps to an iodide. Suzuki-Miyaura cross-couplings involving this common intermediate and various arylboronates allowed to gain access to several vulpinic acids (or methyl pulvinates). Among them, two natural products, vulpinic acid and pinastric acid, were prepared.
Tetronic acid was converted in a few steps to an alkenyl iodide which served as a common precursor for several vulpinic acids (methyl pulvinates), bearing different Ar groups, and obtained via Suzuki-Miyaura cross-couplings.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 48, Issue 37, 10 September 2007, Pages 6421-6424
Journal: Tetrahedron Letters - Volume 48, Issue 37, 10 September 2007, Pages 6421-6424
نویسندگان
Catherine Willis, Ewen Bodio, Yann Bourdreux, Célia Billaud, Thierry Le Gall, Charles Mioskowski,