کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5282049 1385684 2009 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Allyl tetrahydropyranyl ether: a versatile alcohol/thiol protecting reagent
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Allyl tetrahydropyranyl ether: a versatile alcohol/thiol protecting reagent
چکیده انگلیسی

Allyl tetrahydropyranyl ether (ATHPE) can be used as a versatile protecting reagent. In combination with NBS/I2, O-allyl group can easily be replaced by hydroxyls (including tertiary-OH) or thiols, in the molecules comprising other reactive functional groups such as halogen, nitro, acetonide and alkene under mild reaction conditions (near neutral pH and ambient temperature).

Allyl tetrahydropyranyl ether (ATHPE) can be used as a versatile protecting reagent. In combination with NBS/I2, O-allyl group can easily be replaced by hydroxyls (including tertiary-OH) or thiols, in the molecules comprising other reactive functional groups such as halogen, nitro, acetonide and alkene under mild reaction conditions (near neutral pH and ambient temperature).

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 50, Issue 46, 18 November 2009, Pages 6236-6240
نویسندگان
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