کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
52931 | 46892 | 2009 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Clean synthesis of adipic acid catalyzed by complexes derived from heteropoly acid and glycine
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Adipic acid was synthesized from cyclohexene and hydrogen peroxide in high yield of 95.1% and excellent selectivity of 99.8% with heteropoly complexes as catalysts. The heteropoly complexes were prepared from heteropoly acids and glycine, and characterized by TG-DSC, elementary analysis, gravimetry and IR spectroscopy. The catalysts prepared showed more efficient than the corresponding heteropoly acids in the synthesis of adipic acid, and W-based heteropoly compounds exhibited higher activities than Mo-based heteropoly compounds.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 10, Issue 5, 25 January 2009, Pages 464–467
Journal: Catalysis Communications - Volume 10, Issue 5, 25 January 2009, Pages 464–467
نویسندگان
Shuiying Ren, Zhengfeng Xie, Liqin Cao, Xiaopeng Xie, Gaofei Qin, Jide Wang,