کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
52966 | 46892 | 2009 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and characterization of strong acidic mesoporous alumino-silicates constructed of zeolite MCM-22 precursors
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis and characterization of strong acidic mesoporous alumino-silicates constructed of zeolite MCM-22 precursors Synthesis and characterization of strong acidic mesoporous alumino-silicates constructed of zeolite MCM-22 precursors](/preview/png/52966.png)
چکیده انگلیسی
Through two-step crystallization procedure and utilizing cetyltrimethylammonium bromide (CTAB) as a template, a KIT-1-like structural mesoporous aluminosilicate (denoted as MM-22) has been synthesized from zeolite MCM-22 precursors under basic conditions. MM-22 was characterized by XRD, FT-IR, N2 adsorption-desorption, 27Al-MAS NMR and NH3-TPD techniques. The results show that MM-22 is pure mesoporous phase, and constructed of secondary structure units of zeolite MCM-22. Compared with classic Al-MCM-41 and ZSM-5, MM-22 has stronger acidity, and shows higher catalytic activity in the alkylation reaction of phenol with tert-butanol.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 10, Issue 5, 25 January 2009, Pages 631–634
Journal: Catalysis Communications - Volume 10, Issue 5, 25 January 2009, Pages 631–634
نویسندگان
Ke Song, Jingqi Guan, Shujie Wu, Qiubin Kan,