کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
52995 46895 2006 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Hydrogenation of sunflower oil on Pd catalysts in supercritical conditions: Effect of the particle size
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Hydrogenation of sunflower oil on Pd catalysts in supercritical conditions: Effect of the particle size
چکیده انگلیسی

The sunflower oil hydrogenation at conventional conditions is insensitive to the catalyst surface morphology, mostly because the reaction is diffusion controlled. The addition of a supercritical solvent permits the hydrogenation reaction to occur in a homogeneous phase in contact with the solid catalyst.Activity and selectivity were analyzed using supercritical propane and γ-Al2O3 supported Pd catalysts with different particle size. No significant variations were observed in the reaction rate. On the other hand, cis-isomers selectivity and the production of saturated compound were favored in the case of the smallest metallic particle size (<2 nm).Despite that during the reaction there occurred a phase separation, propane was in supercritical state in both phases. Thus, the advantages mentioned regarding mass transfer could still be observed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 7, Issue 6, June 2006, Pages 344–347
نویسندگان
, , , , ,