کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5353349 | 1503672 | 2014 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Further damage induced by water in micro-indentations in phosphate laser glass
ترجمه فارسی عنوان
آسیب های اضافی ناشی از آب در میکرو دندانه ها در شیشه لیزر فسفات
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کلمات کلیدی
شیشه فسفات خوردگی، ترک، نانو انداختن،
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
چکیده انگلیسی
Using a microhardness tester, artificial flaws were made by micro-indentation in N31 Nd-doped phosphate laser glass. Indentation fracture toughness, KIC, was estimated as 0.45-0.53 MPa m1/2 from these indentations. The glasses with indentations were then immersed in ultrapure water to investigate further water-induced damage of these indentations. Stress-enhanced hydrolysis leads to the propagations of radial crack, lateral cracks and microcracks in the subsurface. These crack propagations therefore cause deformation in subsurface to form annular reflections regions around the indentations and further material collapse within imprints. After the residual stresses are exhausted, the leaching plays a more dominated role in glass corrosion in the further immersion. After immersion, the material structure slackens around micro-indentation, which decreases the contact stiffness and results in a lower nano-hardness. For the surface far away from flaws, water immersion presents a weak effect on the near-surface mechanical since the matrix leaching in phosphate glass restricts the formation of hydration layer. During first 20 min immersion, due to higher chemical activity and lower fracture toughness, the radial cracks show a faster propagation in phosphate glass compared with that in K9 silicate glass. For further immersion, crack healing occurs in silicate glass but not in phosphate glass. Analysis shows that the formation of hydration layer on crack walls plays an important role in crack healing in glasses.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 292, 15 February 2014, Pages 267-277
Journal: Applied Surface Science - Volume 292, 15 February 2014, Pages 267-277
نویسندگان
Jiaxin Yu, Qingyun Jian, Weifeng Yuan, Bin Gu, Fang Ji, Wen Huang,