کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
53574 | 46975 | 2015 | 9 صفحه PDF | دانلود رایگان |
• Solvothermal method was successfully used to obtain well-crystallized perovskite.
• Solvothermally prepared perovskites are catalytically active in lean CH4 combustion.
• The highest activity was found for LaMnO3.
• Partial substitution of La by Sr lowers content of Mn4+ on the surface.
Solvothermal synthesis was successfully used to prepare LaMeO3 (Me = Mn, Co, Fe) and La1 − xSrxMnO3 (x = 0.1, 0.3, 0.5), mixed oxides with perovskite-like structure. The prepared materials were examined by X-ray diffraction (XRD), nitrogen adsorption at low temperature (BET), transmission electron microscopy (TEM), decomposition of cyclohexanol (CHOL), temperature programmed reduction with hydrogen (TPRH2), temperature programmed desorption of oxygen (TPDO2) and X-ray photoelectron spectroscopy (XPS). Furthermore, catalytic activity for combustion of 0.6% vol. methane in air (GHSV = 40 000 h−1) was determined.All prepared materials are nanocrystalline and well-crystallized, and they exhibit relatively well-developed specific surface area (9.2–39.2 m2/g). The trigonal structure of the Mn-containing samples corresponds to the structure of the high-temperature bulk phase, which cannot be recovered at ambient conditions. Generally, the Mn-containing materials exhibit higher SSA, more basic character of the surface, lower temperature of maximum H2 consumption and higher catalytic activity in lean methane combustion than the corresponding Co- and Fe-based nanocrystals. The highest catalytic activity for lean methane combustion (100% of CH4 conversion at 451 °C) is observed for LaMnO3. A partial substitution of La by Sr lowers content of Mn4+ on the surface of the corresponding materials, resulting in lower catalytic activity in lean methane combustion.
Figure optionsDownload high-quality image (208 K)Download as PowerPoint slide
Journal: Catalysis Today - Volume 257, Part 1, 15 November 2015, Pages 26–34