کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5363936 | 1388308 | 2008 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Surface-modified mesoporous silica with ferrocene derivatives and its ultrasound-triggered functionality
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
Novel ferrocene derivatives designed as gatekeepers were successfully composed on the pore outlet of amino-functionalized mesoporous silica by post-synthesis grafting where the peptide bond of the amine group (-NH2) of mesoporous silica was linked with the carboxylic acid group (-COOH) of both ends of the ferrocene derivatives. The materials of the amine-functionalized mesoporous silica (NH2-MS) and ferrocene-functionalized mesoporous silica (Fc-CONH-MS) were characterized using X-ray diffractions (XRD), Fourier-transform infrared (FT-IR), N2 sorption isotherms, solid-state NMR spectra, scanning electron microscopy (SEM), energy dispersive X-ray (EDX), transmission electron microscopy (TEM), and UV-vis absorption spectra. The ferrocene attached to the mesoporous silica pore outlet was cleavaged by ultrasound irradiation, which opened the closed-pore outlets, suggesting a possible application for controlled release drug carrier.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 254, Issue 15, 30 May 2008, Pages 4732-4737
Journal: Applied Surface Science - Volume 254, Issue 15, 30 May 2008, Pages 4732-4737
نویسندگان
Eun Jung Kwon, Tai Gyu Lee,