کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5376458 | 1504322 | 2007 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Optical population of free iodine molecule ion-pair states and their RgI2(IP) complexes via RgI2 vdW complexes of valence states correlating with the third dissociation limit
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Optical population of free iodine molecule ion-pair states and their RgI2(IP) complexes via RgI2 vdW complexes of valence states correlating with the third dissociation limit Optical population of free iodine molecule ion-pair states and their RgI2(IP) complexes via RgI2 vdW complexes of valence states correlating with the third dissociation limit](/preview/png/5376458.png)
چکیده انگلیسی
Spectral and kinetic analysis of luminescence in the λ = 220-500 nm spectral range observed after three-step, 532.124 + 1024.48 + 532.24 nm, laser excitation of the I2 + Rg mixtures, Rg = He-Xe, in wide 2. 7-100 Torr Rg pressures shows that one cannot describe the spectral features as well as their dependences on Rg pressures in framework of competition of spontaneous and collision-induced processes in a free iodine molecule. The same conclusion has been drawn after analysis of the papers concerning one-photon laser photolysis of these mixtures. To explain all these data, one has to take into consideration photoexcitation of the RgI2(IP) complexes via the complexes and colliding pairs of rare gases and valence state iodine molecules.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics - Volume 336, Issues 2â3, 27 July 2007, Pages 109-120
Journal: Chemical Physics - Volume 336, Issues 2â3, 27 July 2007, Pages 109-120
نویسندگان
S.S. Lukashov, I.Yu. Novikova, S.A. Poretsky, A.M. Pravilov, A.S. Torgashkova,