کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5425833 | 1395867 | 2006 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Bulk and surface properties of liquid Al-Mg, Au-Sn, and Mg-Tl compound forming alloys Bulk and surface properties of liquid Al-Mg, Au-Sn, and Mg-Tl compound forming alloys](/preview/png/5425833.png)
We have used phenomenological models based on statistical mechanics to study the bulk and surface properties of Au-Sn, Al-Mg, and Mg-Tl binary liquid alloys. Our study reveals that the three alloys are weakly ordered systems with the most stable intermetallic complexes at temperatures of 823Â K, 1073Â K and 923Â K been AuSn, Al3Mg2 and Mg4Tl, respectively. An analysis of Warren-Cowley short-range order parameter indicates that the weakest intermetallic compound is Al-Mg while Au-Sn is observed to be more chemically ordered than Mg-Tl. Furthermore, our surface properties calculations shows that Mg-atom and Sn-atom segregate to the surface over the whole concentration range of Al-Mg and Au-Sn alloys, respectively. In Mg-Tl, there is a competing effect between Tl-atom being drawn into the bulk and at the same time Tl-atom wanting to segregate to the surface over the whole concentration range.
Journal: Surface Science - Volume 600, Issue 10, 15 May 2006, Pages 2122-2128