کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5426833 | 1395908 | 2006 | 7 صفحه PDF | دانلود رایگان |
Reflection absorption infrared spectroscopy (RAIRS) has been used to investigate the adsorption of CO on CeO2âx-supported Pd nanoparticles at room temperature. The results show that when CeO2âx is initially grown on Pt(1Â 1Â 1), a small proportion of the surface remains as bare Pt sites. However, when Pd is deposited onto CeO2âx/Pt(1Â 1Â 1), most of the Pd grows directly on top of the CeO2âx(1Â 1Â 1). RAIR spectra of CO adsorption on 1Â ML Pd/CeO2âx/Pt(1Â 1Â 1) show a broad CO-Pd band, which is inconsistent with a single crystal Pd surface. However, the 5Â ML and 10Â ML Pd/CeO2âx/Pt(1Â 1Â 1) spectra show vibrational bands consistent with the presence of Pd(1Â 1Â 1) and (1Â 0Â 0) faces, suggesting the growth of Pd nanostructures with well defined facets.
Journal: Surface Science - Volume 600, Issue 12, 15 June 2006, Pages 2555-2561