کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5431749 1508823 2017 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effect of sonication and hydrogen peroxide oxidation of carbon nanotube modifiers on the microstructure of pitch-derived activated carbon foam discs
ترجمه فارسی عنوان
اثر سونیک و اکسیداسیون پراکسید هیدروژن اصلاح کننده های نانولوله کربن بر ریز ساختار دیسک های فوم کربن فعال حاصل از زمین
موضوعات مرتبط
مهندسی و علوم پایه مهندسی انرژی انرژی (عمومی)
چکیده انگلیسی

We used carbon nanotubes (CNTs) as modifying particles and potassium hydroxide as a porogen to prepare mesoporous pitch-derived activated carbon discs (ACD) with high surface areas. The parameters investigated in this study included the concentration of CNTs (1%, 2%, 3.5% and 5%), the dispersion of the CNTs in the pitch using a 750 W sonic probe, the oxidation of the CNTs with H2O2, and the aspect ratio of the CNTs. The highest surface area ACD was obtained with 2% oxidized CNTs dispersed in the pitch with the ultrasonic probe (ACD-2%-SO, SBET = 2089 m2 g−1). The ACDs prepared with the sonic probe and with 2 wt% or more of raw and oxidized CNTs exhibited larger mesopore volumes than those ACDs prepared with 1 wt% CNTs. A series of quench tests performed during the foaming process by withdrawal of the carbon from the tube furnace at 673 K, 773 K and 873 K revealed that mesopores in ACD develop at temperatures ranging from 773 K to 873 K, whereas micropores formed between 873 K and 1073 K. The adsorption capacities of N2 and CO2 on ACD-2%-SO were measured with a gravimetric apparatus at 298 K and 303 K at pressures up to 4000 kPa. The uptake of CO2 on ACD-2%-SO at a temperature of 298 K was 3.33 mol/kg at 100 kPa and 11.51 mol/kg at 3496 kPa.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbon - Volume 124, November 2017, Pages 142-151
نویسندگان
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