کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5431933 1508825 2017 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Ultramicroporous carbon with extremely narrow pore distribution and very high nitrogen doping for efficient methane mixture gases upgrading
ترجمه فارسی عنوان
کربن فوق کربن با توزیع بسیار منحنی باریک و دوپینگ نیتروژن بسیار بالا برای بهبود کارآیی گازهای مخلوط متان
موضوعات مرتبط
مهندسی و علوم پایه مهندسی انرژی انرژی (عمومی)
چکیده انگلیسی

It is notably challenging to fabricate heavily heteroatom-doped porous carbonaceous materials with narrow ultramicropore size distributions for highly effective mixed-gas separation. In this study, new carbon-based materials with narrow ultramicropore size (<7 Å) distributions (>95%) and high N doping contents (>10 at%) are fabricated through the pyrolysis of a perchloro-substituted porous covalent triazine-based framework (ClCTF). In particular, the sample prepared at 650 °C (ClCTF-1-650) possesses the highest ultramicropores content (98%) and large N content (12 at%) and demonstrates a very high CH4 and CO2 capacity, as well as a low N2 uptake under ambient conditions. The extraordinarily high CH4/N2 and CO2/N2 selectivities correlate with both the ideal adsorption solution theory (IAST) method and performed dynamic separation experiments (breakthrough experiments). The results reported in this study far exceed the CH4/N2 and CO2/N2 selectivities of previously reported carbon-based adsorbents including various nitrogen-doped ones. These results are believed to be associated with the unusually high N content, as well as the suitably narrow ultramicropore size distribution. This report introduces a new pathway to design porous absorbents with precisely controlled ultramicropores for gas separation.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbon - Volume 122, October 2017, Pages 258-265
نویسندگان
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