کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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5432154 | 1508831 | 2017 | 12 صفحه PDF | دانلود رایگان |
Capacitive deionization (CDI) with high energy efficiency, low cost, and non-secondary pollution is considered an emerging desalination technology. To pursue excellent electrode materials with high electrosorption capacity is highly desired for practical CDI application. In this work, the protic salt-derived porous carbon was synthesized via the direct pyrolysis of the protic salt, i.e., p-phenylenediamine bisulfate ([pPDA][2HSO4]), which was obtained by simply neutralizing p-phenylenediamine with sulfuric acid. The resultant carbon materials possessed large specific surface area, high nitrogen doping, good graphitization and large mesopores. These intrinsic characteristics endowed protic salt-derived porous carbon with excellent electrochemical properties and CDI desalination performance. Particularly, the carbon obtained at 900 °C (C-9) with optimal porous structure (1082 m2 gâ1) and chemical composition (5.2% N) exhibited the best electrochemical property with a specific capacitance of 222.3 F gâ1. The CDI results showed that C-9 had a high electrosorption capacity of 16.5 mg gâ1 in 100 mg Lâ1 NaCl solution and excellent electrosorption stability over 20 times of adsorption-desorption cycles. Furthermore, we demonstrated the dependence of CDI performance on the balance between porous structure and chemical composition. These results imply that the protic salt-derived porous carbon should be a promising electrode material for CDI application.
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Journal: Carbon - Volume 116, May 2017, Pages 21-32