کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5432154 1508831 2017 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A protic salt-derived porous carbon for efficient capacitive deionization: Balance between porous structure and chemical composition
ترجمه فارسی عنوان
کربن متخلخل متشکل از نمک پروتئینی برای خنثی سازی خازنی کارآمد: تعادل بین ساختار متخلخل و ترکیب شیمیایی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی انرژی انرژی (عمومی)
چکیده انگلیسی

Capacitive deionization (CDI) with high energy efficiency, low cost, and non-secondary pollution is considered an emerging desalination technology. To pursue excellent electrode materials with high electrosorption capacity is highly desired for practical CDI application. In this work, the protic salt-derived porous carbon was synthesized via the direct pyrolysis of the protic salt, i.e., p-phenylenediamine bisulfate ([pPDA][2HSO4]), which was obtained by simply neutralizing p-phenylenediamine with sulfuric acid. The resultant carbon materials possessed large specific surface area, high nitrogen doping, good graphitization and large mesopores. These intrinsic characteristics endowed protic salt-derived porous carbon with excellent electrochemical properties and CDI desalination performance. Particularly, the carbon obtained at 900 °C (C-9) with optimal porous structure (1082 m2 g−1) and chemical composition (5.2% N) exhibited the best electrochemical property with a specific capacitance of 222.3 F g−1. The CDI results showed that C-9 had a high electrosorption capacity of 16.5 mg g−1 in 100 mg L−1 NaCl solution and excellent electrosorption stability over 20 times of adsorption-desorption cycles. Furthermore, we demonstrated the dependence of CDI performance on the balance between porous structure and chemical composition. These results imply that the protic salt-derived porous carbon should be a promising electrode material for CDI application.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbon - Volume 116, May 2017, Pages 21-32
نویسندگان
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