کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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5432521 | 1508833 | 2017 | 13 صفحه PDF | دانلود رایگان |
Phase change materials (PCMs) are of interest in many applications which may require shape-stabilization. In this study, a graphene oxide aerogel (GOxA) reinforced paraffin PCM composite is developed, effectively reinforcing and shape-stabilizing the paraffin.The molecular and diffraction characterizations suggest that the GOxA network potentially affects paraffin's crystallization. The mechanical characterizations using durometer and nanoindentation show that the composite is 3∼7× harder than pure paraffin and maintains significant strength even above paraffin's melting temperature. Moreover, the composite is much less strain-rate sensitive than paraffin. The reinforcement via GOxA is much beyond the prediction by the rule-of-mixture, implying a strong GOxA-paraffin interfacial bonding.To our best knowledge, this is the first study on the mechanical behavior of paraffin and GOxA-PCM composite, providing critical insights into their behavior. Additionally, the relationship between the hardness and durometer index first-ever developed here will enable the quantitative durometer testing on materials for many other applications at different ambient conditions due to its versatility and simplicity.
Journal: Carbon - Volume 114, April 2017, Pages 334–346