کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5438177 1398181 2017 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation and characterization of SO3-doped barium borosilicate glass-ceramics containing zirconolite and barite phases
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Preparation and characterization of SO3-doped barium borosilicate glass-ceramics containing zirconolite and barite phases
چکیده انگلیسی
In order to improve the solubility of actinides and sulfate in the glass matrix, barium borosilicate glass-ceramics containing zirconolite and barite crystalline phases were developed. The effects of SO3 addition (0-8 wt%) on crystalline phases, microstructure, and chemical durability of glass-ceramics belonging to SiO2-B2O3-Na2O-BaO-CaO-TiO2-ZrO2-Nd2O3-SO3 system were mainly studied. The results show that glass transformation temperature decreases slightly with increasing SO3 content. The main crystalline phase is zirconolite for all of the samples. When the addition SO3 content is higher or equal to 4 wt%, rice-shaped barite crystals appear in the bulk of glass-ceramics. Barite phase was formed during the melting stage. X-ray fluorescence analysis indicates that about 1.3 wt% of SO3 can be incorporated in the glass-ceramics when the addition content of SO3 is 6 wt%. S element mainly distributes in the barite crystals. The decomposition of sulfate mainly occurs during the melting process. Moreover, the addition of a certain content (≤6 wt%) of sulfate has no significant influence on the chemical durability of barium borosilicate glass-ceramics.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 43, Issue 1, Part A, January 2017, Pages 534-539
نویسندگان
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