کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5439030 1398190 2017 51 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Magnetite-based glass-ceramics prepared by controlled crystallization of borosilicate glasses: Effect of nucleating agents on magnetic properties and relaxation
ترجمه فارسی عنوان
شیشه سرامیک مبتنی بر مگنتیت تهیه شده توسط کریستالسیون کنترل شده از عینک بورسیلیکات: اثر عوامل هسته ای بر خواص مغناطیسی و آرام سازی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
چکیده انگلیسی
The specific magnetic structure and magnetic relaxation phenomena in magnetite nanoentities grown in a glassy matrix by controlled crystallization of Fe-containing borosilicate and boroaluminosilicate glasses in the presence of two types of nucleating agents, Cr2O3 and P2O5, were investigated. The structure, morphology and magnetic properties are strongly influenced by the nucleating agents. Cr2O3 generates magnetite-based glass ceramics with magnetite configurations showing an upward relaxation of magnetization at low and high temperatures but downward at intermediate temperatures. The magnetite grown with P2O5 displays only downward relaxation but with different signs of the temperature derivative of the relaxation rate S in different temperature ranges. The observed effects are discussed with respect to the following factors: i) the existence of a multimodal size distribution of the magnetite (nano)particles as revealed by high resolution electron microscopy; ii) the degree of occupation of different sublattices of the magnetite structure with Fe3+ and Fe2+ ions; and iii) the interplay between the relaxation mechanisms in different temperature ranges.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 43, Issue 3, 15 February 2017, Pages 3405-3413
نویسندگان
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